A promising monolayer membrane for oxygen separation from harmful gases: nitrogen-substituted polyphenylene.

نویسندگان

  • Ruifeng Lu
  • Zhaoshun Meng
  • Dewei Rao
  • Yunhui Wang
  • Qi Shi
  • Yadong Zhang
  • Erjun Kan
  • Chuanyun Xiao
  • Kaiming Deng
چکیده

We theoretically demonstrate that N-substitutional doping dramatically reduces the diffusion barrier for oxygen passing through the pores of polyphenylene, leading to a massive enhancement in O2 selectivity over various harmful gases with excellent permeance at appropriate temperatures for O2 across an N-doped polyphenylene in a unit cell.

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عنوان ژورنال:
  • Nanoscale

دوره 6 17  شماره 

صفحات  -

تاریخ انتشار 2014